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Rzokee, Abdulsatar Abduljabbar
- Preparation and spectroscopic studies of charge-transfer complexes of 2, 2-bipyridine and hydroxy benzo pyridine as electron donors with chloranilic acid, 3, 5 di nitro benzoic acid and p-nitro phenol as electron acceptors in methanol
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Authors
Affiliations
1 Department of Chemistry, Aligarh Muslim University, Aligarh
1 Department of Chemistry, Aligarh Muslim University, Aligarh
Source
Asian Journal of Research in Chemistry, Vol 6, No 8 (2013), Pagination: 772-793Abstract
The reactions between 2,2 bipyridine (Bpy) and hydroxy benzo pyridine (8HQ) as electron donors with some acceptors such as chloranilic acid (CAA), 3, 5 di nitro benzoic acid (DNBA) and p-nitro phenol (PNP) were studied at room temperature. Based on FT- IR spectrum of the solid CT complexes along with the UV- visible spectroscopy for the reactions, the data obtained indicate the formation of 1:1 charge-transfer complexes. The infrared and 1H NMR spectroscopic data and XRD spectrum indicate a charge-transfer interaction associated with a proton migration from the acceptor to the donor followed by intermolecular hydrogen bondingKeywords
Charge- Transfer Complexes, 2, 2 Bipyridine, Hydroxy Benzo Pyridine, FT- IR, UV- Visible, 1H NMR, XRD
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